Lithium Borohydride
Lithium Borohydride
Categories: Lithium series,
Lithium Borohydride (LiBH₄) – High-Efficiency Reducing Agent & Hydrogen Storage Material
Product Overview
Chemical Name: Lithium Borohydride
CAS Number: 16949-15-8
Molecular Formula: LiBH₄
Molecular Weight: 21.78 g/mol
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    Product Description

    Chemical & Physical Properties

    • Appearance: White crystalline powder
    • Melting Point: ~280°C (Decomposes)
    • Boiling Point: Decomposes before boiling
    • Density: ~0.67 g/cm³
    • Solubility:
      • Soluble in ethers such as THF
      • Reacts with water, releasing hydrogen gas (H₂)
    • Stability: Stable under dry, inert conditions

     


     

    Key Features & Benefits

    ✅ Powerful Reducing Agent: Highly efficient for organic synthesis and pharmaceutical applications
    ✅ Hydrogen-Rich Compound: High gravimetric hydrogen density for energy storage research
    ✅ Selective Reduction Ability: Converts esters, amides, and nitriles to alcohols and amines
    ✅ Anhydrous & High-Purity Grades Available: Suitable for moisture-sensitive reactions

     


     

    Industrial & Laboratory Applications

    Organic & Pharmaceutical Synthesis

    • Reduction Reactions:
      • Converts esters, ketones, and aldehydes to their corresponding alcohols.
      • Used for amine and borane complex formation.
    • Selective Hydrogenation:
      • Efficiently reduces nitriles and imines to primary amines.

    Energy Storage & Fuel Cell Research

    • Hydrogen Storage Material:
      • High hydrogen content (~18.4% by weight) makes it a potential material for hydrogen fuel applications.
      • Thermally decomposes to release hydrogen gas under controlled conditions.

    Battery & Electrochemical Applications

    • Ionic Conductor for Solid-State Batteries:
      • Investigated as a lithium-ion conductor in advanced battery systems.
    • Electrolyte Component in High-Energy Cells:
      • Used in next-generation energy storage technologies.

     


     

    Handling & Safety Considerations

    ⚠️ Highly Reactive & Moisture-Sensitive!

    • Water Sensitivity: Reacts with water, releasing flammable hydrogen gas (H₂).
    • Air Sensitivity: Decomposes upon exposure to moisture, forming lithium hydroxide and borates.
    • Handling Precautions:
      • Store and handle under anhydrous conditions.
      • Use only in a dry, inert atmosphere (glovebox or Schlenk techniques).

     


     

    Storage & Packaging

    • Storage Conditions:
      • Keep in sealed containers under dry argon or nitrogen.
      • Store in a cool, moisture-free environment away from ignition sources.
    • Personal Protective Equipment (PPE):
      • Chemical-resistant gloves, safety goggles, and flame-resistant lab coats.
      • Use in well-ventilated areas with proper safety protocols.

    Available in:

    • 1kg sealed moisture-proof cylinder
    • Custom purity levels for research and industrial applications

     

    Application

    Lithium Borohydride (LiBH₄) is a white crystalline solid known for its strong reducing properties and high hydrogen storage capacity. It is widely used in organic synthesis, fuel cell technology, and battery research. As a powerful reducing agent, LiBH₄ is employed in the selective reduction of carbonyl compounds, esters, and imines. Additionally, its exceptional hydrogen content makes it a promising material for hydrogen storage applications in energy sectors.

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